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OLIVEIRA,DÉBORA R. DE; NEPOMUCENO,DELCI D.; CASTRO,ROSANE N.; BRAZ FILHO,RAIMUNDO; CARVALHO,MÁRIO G. DE. |
ABSTRACT This study aims to identify special metabolites in polar extracts from Urochloa humidicola (synonym Brachiaria humidicola) that have allelopathic effects and induce secondary photosensitization in ruminants. The compounds were isolated and identified via chromatographic and spectroscopic techniques. The compounds 4-hydroxy-3-methoxy-benzoic acid, trans-4-hydroxycinnamic acid, and p-hydroxy-benzoic acid; the flavonols isorhamnetin-3-O-β-d-glucopyranoside and methyl quercetin-3-O-β-d-glucuronate; and kaempferitrin, quercetin-3-O-α-l-rhamnopyranoside, and tricin were identified in the extract from the leaves of Urochloa humidicola. Two furostanic saponins, namely, dioscin and... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Brachiaria humidicola; Flavonoids; Steroidal saponins; Urochloa. |
Ano: 2017 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652017000300789 |
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Brum,Karine Bonucielli; Haraguchi,Mitsue; Garutti,Mirella Biasoli; Nóbrega,Fernanda Nogarol; Rosa,Beneval; Fioravanti,Maria Clorinda Soares. |
Brachiaria species contain steroidal saponins and are involved in outbreaks of hepatogenous photosensitization. This research presents the levels of a steroidal saponin, protodioscin, in the seeds and aerial parts of B. brizantha and B. decumbens during different developmental stages (growth, bloom, fructification and seed fall). The butanolic fraction of the ethanolic extract of each stage was submitted to thin layer chromatography (TLC) and spectrophotometric analysis through the Ehrlich reagent in 515nm. The chromatograms in TLC of the butanolic fraction of B. brizantha and B. decumbens showed similar spots as the protodioscin standard. The estimated level of protodioscin isomers in B. brizantha and B. decumbens ranged from 0.5% to 2.1%, having the... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Brachiaria spp.; Photosensitization; Protodioscin; Spectrophotometry; Steroidal saponins. |
Ano: 2009 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-84782009000100049 |
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